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991.
《Physics and Chemistry of Liquids》2012,50(6):641-648
The complex formation reaction between N,N′-bis(2-pyridylmethylidene)-1,2-diiminoethane (BPIE) di-Schiff base ligand as an electron donor and iron(III) chloride as an electron acceptor have been studied spectrophometrically in methanol at 28°C. The values of equilibrium constants, K and molar absorptivities, ε were obtained from the Benesi–Hildebrand, Scott and Foster–Hammick–Wardley equations. The results indicate the formation of 1?:?1 charge transfer complex. The absorption band energy of the complex, E CT, the ionization potential of the BPIE Schiff base ligand, I D, and the Gibbs energy changes of the above reaction, ΔG 0, were calculated. Finally, the kinetics of the complex formation reaction were studied and was found to be second-order in each reactant. The values of the rate constants of the forward and reverse reactions k 1 and k ?1 were determined. 相似文献
992.
993.
994.
《Journal of Coordination Chemistry》2012,65(21):3740-3750
Complexes [M(L)(L′)Cl?·?H2O], where M?=?Co(II), Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II), L?=?ligand derived from reaction between benzofuran-2-carbohydrazide and 3,4,5-trimethoxybenzaldehyde (TMeOBFC) and L′?=?2-aminothiophenol (2-atp), have been synthesized. The structures of the complexes have been proposed from analytical data, IR, UV-Vis, 1H NMR, direct analysis in real time-mass spectra, ESR spectral data, magnetic, and thermal studies. The complexes are soluble in DMF and DMSO. Molar conductance values indicate that the complexes are non-electrolytes. Antibacterial and antifungal activities of the ligands and their metal complexes have been obtained against bacteria Escherichia coli and Staphylococcus aureus and against fungi Aspergillus niger and Aspergillus flavus. 相似文献
995.
《Journal of Coordination Chemistry》2012,65(17):1531-1539
Two new lead(II) complexes containing nitrite, [Pb(L)2(NO2)2], L?=?1,10-phenanthroline (phen) or 2,2′-bipyridine (bpy), have been synthesized and characterized. The crystal structure of [Pb(phen)2(NO2)2] shows monomeric units. The coordination number is eight (four from “phen” ligands and four nitrite anions), weak interaction of lead(II) with oxygen atoms of adjacent molecules produce dimer units in the solid state. The arrangement of ligands exhibits a coordination hole around the lead(II), occupied possibly by a stereoactive lone pair of electrons on lead(II), and the coordination around lead is hemidirected. There is a π–π stacking interaction between the parallel aromatic rings that may help to increase the “gap” around lead(II). 相似文献
996.
997.
《Journal of Coordination Chemistry》2012,65(5):819-827
A series of anionic five-coordinate binary oxorhenium(V) complexes with dithiolato ligands, Bu4N[ReO(L1)2] (1a), Bu4N[ReO(L2)2] (1b), and Bu4N[ReO(L3)2] (1c), and a series of neutral octahedral ternary oxorhenium(V) complexes of mixed dithiolato and bipyridine ligands, [ReO(L1)(bpy)Cl] (2a), [ReO(L2)(bpy)Cl] (2b), and [ReO(L3)(bpy)Cl] (2c) (where L1H2 = ethane-1,2-dithiol, L2H2 = propane-1,3-dithiol, L3H2 = toluene-3,4-dithiol, and bpy = 2,2′-bipyridine), were isolated and characterized by physicochemical and spectroscopic methods. The solid state structure of 1c was established by X-ray crystallography. All the mononuclear oxorhenium(V) complexes are diamagnetic. The redox behavior of all the complexes has been studied voltammetrically. 相似文献
998.
《Journal of Coordination Chemistry》2012,65(3):195-205
Abstract ESR investigation of the γ -ray irradiated Co(III) complexes have been carried out. The identification and the classification of the irradiation products on the basis of the ESR signal patterns, and the electronic and the spin states of the products are discussed. Co(III) complexes are reduced by the γ irradiation into Co(II) complexes, where the produced Co(II) ions have low spin configurations, S = ½. Authors refer to these particular spin states as hot ions. 相似文献
999.
《Journal of Coordination Chemistry》2012,65(11):2004-2011
The reaction of Cu(Ac)2·4H2O with 2-[(3,5-dichloro-2-hydroxy-benzylidene)-amino]-2hydroxymethyl-propane-1,3-diol (H4L) and 4,4′-bipyridyl-N,N′-dioxide (4,4′-bipy-NO) in DMF under solvothermal conditions leads to the formation of a di-radical dinuclear copper complex [Cu2(4,4′-bipy-NO)(dcdmap)4] (1) (dcdmap is the anion of 2,4-dichloro-6dimethylaminomethyl-phenol, synthesized by an in situ reaction). Compound 1 was characterized by elemental analysis, IR spectroscopy, and X-ray single-crystal diffraction. Complex 1 displays dominant anti-ferromagnetic interaction between oxyradicals and copper ion and oxyradical. 相似文献
1000.
《Journal of Coordination Chemistry》2012,65(5):825-832